Document Detail


Self-assembly of a covalent organic cage with exceptionally large and symmetrical interior cavity: the role of entropy of symmetry.
MedLine Citation:
PMID:  23422938     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
An exceptionally large size cuboctahedral imine cage is obtained from small size organic molecules in a thermodynamically driven [8+12] cyclocondensation. This is a demonstration of the role of entropy of symmetry as a driving force in reversible reactions.
Authors:
Paweł Skowronek; Beata Warżajtis; Urszula Rychlewska; Jacek Gawroński
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-2-20
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Feb 
Date Detail:
Created Date:  2013-2-20     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, A. Mickiewicz University, Poznań, Poland. Pawel.Skowronek@amu.edu.pl.
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