Document Detail


Self-Assembled Poly(N-methylaniline)-Lignosulfonate Spheres: From Silver-Ion Adsorbent to Antimicrobial Material.
MedLine Citation:
PMID:  23818407     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Self-assembled poly(N-methylaniline)-lignosulfonate (PNMA-LS) composite spheres with reactive silver-ion adsorbability were prepared from N-methylaniline by using lignosulfonate (LS) as a dispersant. The results show that the PNMA-LS composite consisted of spheres with good size distribution and an average diameter of 1.03-1.27 μm, and the spheres were assembled by their final nanofibers with an average diameter of 19-34 nm. The PNMA-LS composite spheres exhibit excellent silver-ion adsorption; the maximum adsorption capacity of silver ions is up to 2.16 g g(-1) at an adsorption temperature of 308 K. TEM and wide-angle X-ray results of the PNMA-LS composite spheres after absorption of silver ions show that silver ions are reduced to silver nanoparticles with a mean diameter of about 11.2 nm through a redox reaction between the PNMA-LS composite and the silver ions. The main adsorption mechanism between the PNMA-LS composite and the silver ions is chelation and redox adsorption. In particular, a ternary PNMA-LS-Ag composite achieved by using the reducing reaction between PNMA-LS composite spheres and silver ions can be used as an antibacterial material with high bactericidal rate of 99.95 and 99.99 % for Escherichia coli and Staphylococcus aureus cells, respectively.
Authors:
Qiu-Feng Lü; Jia-Yin Zhang; Jun Yang; Zhi-Wei He; Chang-Qing Fang; Qilang Lin
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-7-1
Journal Detail:
Title:  Chemistry (Weinheim an der Bergstrasse, Germany)     Volume:  -     ISSN:  1521-3765     ISO Abbreviation:  Chemistry     Publication Date:  2013 Jul 
Date Detail:
Created Date:  2013-7-2     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9513783     Medline TA:  Chemistry     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
College of Materials Science and Engineering, Fuzhou University, 2 Xueyuan Road, Fuzhou 350116 (P.R. China), Fax: (+86) 591-22866539. qiufenglv@163.com.
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