Document Detail


Selenium containing imidazolium salt in designing single source precursors for silver bromide and selenide nano-particles.
MedLine Citation:
PMID:  23292353     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The AgBr and Ag(2)Se nanoparticles (NPs) have been synthesized for the first time from two single source precursors ([Ag(2)()(2)Br(2)] () and [Ag(-HBr)(2)]BF(4) () respectively) designed using the same ligand 3-benzyl-1-(2-phenylselanyl-ethyl)-3H-imidazolium bromide (). The ODE-ODA-OA (1 : 1 : 2) and TOP-OA (1 : 2) are most suitable solvents for thermolysis of and respectively, resulting in the NPs. The composition of the solvent used in thermolysis affects the purity of NPs. The bonding of in is unique, as it has a pre-carbene site intact.
Authors:
Hemant Joshi; Kamal Nayan Sharma; Ved Vati Singh; Pradhumn Singh; Ajai Kumar Singh
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-7
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-7     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110016, India. aksingh@chemistry.iitd.ac.in ajai57@hotmail.com.
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