| Selective transformations of organic compounds by imidozirconocene complexes. | |
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MedLine Citation:
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PMID: 12469354 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Imidozirconocene complexes (Cp(2)Zr=NR(THF)) possess a rich reaction chemistry, in contrast to many imido complexes of later transition metals. The synthesis and structural characteristics of these compounds are briefly described, along with a qualitative molecular orbital description of the metallocene-imido interaction. Imidozirconocene complexes react at the Zr=N linkage with a variety of X-H bonds, and undergo overall [2 + 2] cycloaddition reactions with a wide range of unsaturated organic and organometallic compounds. Results of studies detailing the scope and mechanism of these reactions are presented herein, along with applications to catalytic hydroamination, imine metathesis, and asymmetric transformations. |
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Authors:
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Andrew P Duncan; Robert G Bergman |
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Publication Detail:
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Type: Journal Article; Research Support, U.S. Gov't, P.H.S. |
Journal Detail:
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Title: Chemical record (New York, N.Y.) Volume: 2 ISSN: 1527-8999 ISO Abbreviation: Chem Rec Publication Date: 2002 |
Date Detail:
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Created Date: 2002-12-06 Completed Date: 2004-07-14 Revised Date: 2007-11-14 |
Medline Journal Info:
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Nlm Unique ID: 101085550 Medline TA: Chem Rec Country: United States |
Other Details:
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Languages: eng Pagination: 431-45 Citation Subset: IM |
Copyright Information:
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Copyright 2002 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. |
Affiliation:
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Department of Chemistry, University of Californa, Berkley, California 94720, USA. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Alkenes
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chemistry Alkynes / chemistry Azides / chemistry Catalysis Imines / chemistry* Molecular Conformation Molecular Structure Nitrogen / chemistry Organic Chemicals / chemical synthesis*, chemistry* Organometallic Compounds / chemistry* Zirconium / chemistry* gamma-Aminobutyric Acid / chemistry |
| Grant Support | |
ID/Acronym/Agency:
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GM-25459/GM/NIGMS NIH HHS; R01 GM025459-24/GM/NIGMS NIH HHS |
| Chemical | |
Reg. No./Substance:
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0/Alkenes; 0/Alkynes; 0/Azides; 0/Imines; 0/Organic Chemicals; 0/Organometallic Compounds; 1291-32-3/Zirconocene dichloride; 56-12-2/gamma-Aminobutyric Acid; 7440-67-7/Zirconium; 7727-37-9/Nitrogen |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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