| Selective switchable iron-catalyzed hydrosilylation of carboxylic acids. | |
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MedLine Citation:
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PMID: 22992694 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Selective reduction of carboxylic acids either to aldehydes or alcohols is achieved using a one pot procedure based on iron-catalyzed hydrosilylations. Using phenylsilane and (COD)Fe(CO)(3) catalyst under UV-irradiation at rt, alcohols were obtained specifically in good yields, whereas aldehydes were selectively obtained using TMDS and (t-PBO)Fe(CO)(3) catalyst under thermal activation. |
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Authors:
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Luis C Misal Castro; Haoquan Li; Jean-Baptiste Sortais; Christophe Darcel |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-9-20 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2012 Sep |
Date Detail:
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Created Date: 2012-9-20 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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UMR 6226 CNRS-Université Rennes1 "Institut des Sciences Chimiques de Rennes" - Centre of Catalysis and Green Chemistry - "Organometallics, Materials and Catalysis" 35042 RENNES cedex, France. jean-baptiste.sortais@univ-rennes1.fr christophe.darcel@univ-rennes1.fr. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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