Document Detail


Selective switchable iron-catalyzed hydrosilylation of carboxylic acids.
MedLine Citation:
PMID:  22992694     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Selective reduction of carboxylic acids either to aldehydes or alcohols is achieved using a one pot procedure based on iron-catalyzed hydrosilylations. Using phenylsilane and (COD)Fe(CO)(3) catalyst under UV-irradiation at rt, alcohols were obtained specifically in good yields, whereas aldehydes were selectively obtained using TMDS and (t-PBO)Fe(CO)(3) catalyst under thermal activation.
Authors:
Luis C Misal Castro; Haoquan Li; Jean-Baptiste Sortais; Christophe Darcel
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-20
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-20     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
UMR 6226 CNRS-Université Rennes1 "Institut des Sciences Chimiques de Rennes" - Centre of Catalysis and Green Chemistry - "Organometallics, Materials and Catalysis" 35042 RENNES cedex, France. jean-baptiste.sortais@univ-rennes1.fr christophe.darcel@univ-rennes1.fr.
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