| Selective reduction of condensed N-heterocycles using water as a solvent and a hydrogen source. | |
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MedLine Citation:
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PMID: 23313913 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The reduction of unprotected indoles and quinolines is described using water as a hydrogen source. The method is based on the application of a RANEY® type Ni-Al alloy in an aqueous medium. During the reaction the Al content of the alloy, used as reductants, reacts with water in situ providing hydrogen and a RANEY® Ni catalyst, thus the alloy serves as a hydrogen generator as well as a hydrogenation catalyst. The simplicity and efficacy of the method are illustrated by the selective reduction of a variety of substituted indoles and quinolines to indolines and tetrahydroquinolines, respectively. |
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Authors:
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Hyejin Cho; Fanni Török; Béla Török |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-14 |
Journal Detail:
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Title: Organic & biomolecular chemistry Volume: - ISSN: 1477-0539 ISO Abbreviation: Org. Biomol. Chem. Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-14 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101154995 Medline TA: Org Biomol Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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University of Massachusetts Boston, 100 Morrissey Blvd., Boston, MA, USA. bela.torok@umb.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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