Document Detail


Selective electrodes for silver based on polymeric membranes containing cali.
MedLine Citation:
PMID:  11225827     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Silver ion-selective electrodes were prepared with polymeric membranes based on two calix[4]arene derivatives functionalized by two hydroxy and two benzothiazolylthioethoxy groups. The electrodes all gave a good Nernstian response of 58mV decade(-1) for silver in the activity range 5 x 10(-6)-10(-1) M, the limits of detection reached 10(-5.8) M and exhibited high selectivity towards alkali, alkaline earth and some transition metal ions. The electrode was used as indicator electrode in titrations of Ag+ with Cl- ion.
Authors:
L Chen; X Zeng; X He; Z Zhang
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Fresenius' journal of analytical chemistry     Volume:  367     ISSN:  0937-0633     ISO Abbreviation:  Fresenius J Anal Chem     Publication Date:  2000 Jul 
Date Detail:
Created Date:  2001-02-27     Completed Date:  2001-04-05     Revised Date:  2003-10-31    
Medline Journal Info:
Nlm Unique ID:  9114077     Medline TA:  Fresenius J Anal Chem     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  535-8     Citation Subset:  -    
Affiliation:
Department of Chemistry, Nankai University, Tianjin, China.
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