Document Detail


γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.
MedLine Citation:
PMID:  23145431     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).
Authors:
Sean M Smith; Gia L Hoang; Rhitankar Pal; Mohammad O Bani Khaled; Liberty S W Pelter; Xiao Cheng Zeng; James M Takacs
Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, U.S. Gov't, Non-P.H.S.    
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  48     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Dec 
Date Detail:
Created Date:  2012-11-22     Completed Date:  2013-05-06     Revised Date:  2014-01-10    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  12180-2     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Alkenes / chemistry*
Boron / chemistry*
Catalysis
Models, Molecular
Molecular Conformation
Stereoisomerism
Substrate Specificity
Grant Support
ID/Acronym/Agency:
GM100101/GM/NIGMS NIH HHS; R01 GM100101/GM/NIGMS NIH HHS
Chemical
Reg. No./Substance:
0/Alkenes; N9E3X5056Q/Boron
Comments/Corrections

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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