| Selective adsorption of D- and L-phenylalanine on molecularly-imprinted polymerized organogels formed using polymerizable gelator N-octadecyl maleamic acid. | |
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MedLine Citation:
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PMID: 18925620 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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The polymerizable gelator N-octadecyl maleamic acid (ODMA) can self-assemble in selected polymerizable organic solvents, such as 2-hydroxyethyl methacrylate (HEMA) and methylacrylic acid (MAA) to form thermally stable polymerizable organogels. A mixture consisting of HEMA and MAA as the monomer and functional monomer, PEG dimethacrylates (PEG200DMA) as the crosslinker, BOC-L-phenylalanine (BPA) or L-phenylalanine ethyl ester (PEE) as the chiral templates, was gelatinized by ODMA firstly and subsequently polymerized by in situ UV irradiation or thermal initiation. The molecularly imprinted polymerized organogels were obtained after the removal of the templates through ethanol extraction. Selective adsorption of D- and L-phenylalanine was performed on the polymerized organogels. The results indicate rather high adsorption efficiency obtained for L-phenylalanine compared with that for D-phenylalanine, which was found to be dependent on the concentrations of ODMA, content of template, and the method of polymerization. Herein, the concentration of ODMA in the organogels played an important role for the adsorption efficiency of D- and L-phenylalanine. |
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Authors:
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Shengzu Zhang; Xinjian Fu; Hong Wang; Yajiang Yang |
Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Journal of separation science Volume: 31 ISSN: 1615-9314 ISO Abbreviation: J Sep Sci Publication Date: 2008 Dec |
Date Detail:
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Created Date: 2008-11-17 Completed Date: 2009-01-22 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101088554 Medline TA: J Sep Sci Country: Germany |
Other Details:
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Languages: eng Pagination: 3782-7 Citation Subset: IM |
Affiliation:
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School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, China. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Adsorption Cross-Linking Reagents / chemistry Gels / chemistry* Maleates / chemistry* Methacrylates / chemistry Molecular Imprinting Molecular Structure Phenylalanine / chemistry* Solvents / chemistry Stereoisomerism |
| Chemical | |
Reg. No./Substance:
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0/Cross-Linking Reagents; 0/Gels; 0/Maleates; 0/Methacrylates; 0/Solvents; 557-24-4/maleamic acid; 63-91-2/Phenylalanine; 79-41-4/methacrylic acid; 868-77-9/hydroxyethyl methacrylate |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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