Document Detail


Selective synthesis of either isoindole- or isoindoline-1-carboxylic acid esters by Pd(0)-catalyzed enolate arylation.
MedLine Citation:
PMID:  20738127     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Two efficient palladium-catalyzed intramolecular α-arylation reactions of α-amino acid esters have been developed that allow either 1-isoindolecarboxylic acid esters or the corresponding isoindolines to be selectively synthesized simply by a slight change of reaction conditions.
Authors:
Daniel Solé; Olga Serrano
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  75     ISSN:  1520-6904     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2010 Sep 
Date Detail:
Created Date:  2010-09-10     Completed Date:  2011-01-11     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  6267-70     Citation Subset:  IM    
Affiliation:
Laboratori de Química Orgànica, Facultat de Farmàcia, and Institut de Biomedicina, Universitat de Barcelona, 08028 Barcelona, Spain. dsole@ub.edu
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MeSH Terms
Descriptor/Qualifier:
Amino Acids / chemistry*
Carboxylic Acids / chemical synthesis*,  chemistry
Catalysis
Cyclization
Esters / chemical synthesis*,  chemistry*
Isoindoles / chemical synthesis*,  chemistry
Molecular Structure
Palladium / chemistry*
Stereoisomerism
Chemical
Reg. No./Substance:
0/Amino Acids; 0/Carboxylic Acids; 0/Esters; 0/Isoindoles; 7440-05-3/Palladium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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