| Selective Synthesis of a [3]Rotaxane Consisting of Size-Complementary Components and Its Stepwise Deslippage. | |
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MedLine Citation:
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PMID: 22519824 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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An α-cyclodextrin-based size-complementary [3]rotaxane with an alkylene axle was selectively synthesized in one pot via an end-capping reaction with 2-bromophenyl isocyanate in water. Thermal degradation of the [3]rotaxane product yielded not only the original components but also the [2]rotaxane. Thermodynamic studies suggested a stepwise deslippage process. |
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Authors:
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Yosuke Akae; Hisashi Okamura; Yasuhito Koyama; Takayuki Arai; Toshikazu Takata |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-4-20 |
Journal Detail:
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Title: Organic letters Volume: - ISSN: 1523-7052 ISO Abbreviation: - Publication Date: 2012 Apr |
Date Detail:
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Created Date: 2012-4-23 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 (H-126), Ookayama, Meguro, Tokyo 152-8552, Japan, and Research Laboratory, LINTEC Corporation, 5-14-42, Nishiki-cho, Warabi-shi, Saitama 335-0005, Japan. |
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