Document Detail


Selective perborate signaling by deprotection of fluorescein and resorufin acetates.
MedLine Citation:
PMID:  20222739     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The acetate derivatives of fluorescein and resorufin exhibited a prominent turn-on type signaling behavior toward BO(3)(-) ions over other common anions. Signaling is based on the selective deprotection of acetate groups by perborate, which resulted in significant chromogenic and fluorogenic signaling. Compound 1 also exhibited a pronounced perborate selectivity over other commonly used oxidants in 90% aqueous acetonitrile solution.
Authors:
Myung Gil Choi; Sunyoung Cha; Ji Eun Park; Haekyung Lee; Hye Lim Jeon; Suk-Kyu Chang
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Organic letters     Volume:  12     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2010 Apr 
Date Detail:
Created Date:  2010-03-26     Completed Date:  2010-06-24     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  1468-71     Citation Subset:  IM    
Affiliation:
Department of Chemistry, Chung-Ang University, Seoul 156-756, Korea.
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MeSH Terms
Descriptor/Qualifier:
Borates / chemistry*
Fluorescein / chemistry*
Molecular Structure
Oxazines / chemistry*
Chemical
Reg. No./Substance:
0/Borates; 0/Oxazines; 1152-14-3/resorufin acetate; 2321-07-5/Fluorescein

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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