Document Detail


Selective Alkylation of Amines with Alcohols by Cp*-Iridium(III) Half-Sandwich Complexes.
MedLine Citation:
PMID:  23286312     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
[Cp*Ir(Pro)Cl] (Pro = prolinato) was identified among a series of Cp*-iridium half-sandwich complexes as a highly reactive and selective catalyst for the alkylation of amines with alcohols. It is active under mild conditions in either toluene or water without the need for base or other additives, tolerates a wide range of alcohols and amines, and gives secondary amines in good to excellent isolated yields.
Authors:
Alexander Wetzel; Simone Wöckel; Mathias Schelwies; Marion K Brinks; Frank Rominger; Peter Hofmann; Michael Limbach
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-3
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
CaRLa - Catalysis Research Laboratory , Im Neuenheimer Feld 584, 69120 Heidelberg, Germany, BASF S E, Synthesis & Homogeneous Catalysis, Carl-Bosch-Straße 38, 67056 Ludwigshafen, Germany, and Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg , Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
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