Document Detail


Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes--a new method for the preparation of silyl ester.
MedLine Citation:
PMID:  18941497     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
Ru(3)(CO)(12)/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru(3)(CO)(12) and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 degrees C in good and high yields.
Authors:
Guo-Bin Liu; Hong-Yun Zhao
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Publication Detail:
Type:  Journal Article     Date:  2008-07-30
Journal Detail:
Title:  Beilstein journal of organic chemistry     Volume:  4     ISSN:  1860-5397     ISO Abbreviation:  Beilstein J Org Chem     Publication Date:  2008  
Date Detail:
Created Date:  2008-10-22     Completed Date:  2010-05-20     Revised Date:  2013-05-23    
Medline Journal Info:
Nlm Unique ID:  101250746     Medline TA:  Beilstein J Org Chem     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  27     Citation Subset:  -    
Affiliation:
Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, P.R.China. liuguobin@fudan.edu.cn
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