Document Detail


Ru-NO and Ru-NO2 bonding linkage isomerism in cis-[Ru(NO)(NO)(bpy)2](2+/+) complexes - a theoretical insight.
MedLine Citation:
PMID:  24781307     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Ruthenium nitrosyl complexes have received considerable attention due to the fact that they are able to store, transfer and release NO in a controlled manner. It is well-known that the NO reactivity of ruthenium nitrosyl complexes can be modulated with the judicious choice of equatorial and axial ligands. In this piece of research we elucidate the nature of the Ru-NO and Ru-NO2 bonding in a cis-[Ru(NO)(NO2)(bpy)2](2+) complex energy decomposition (Su-Li EDA) and topological (e.g., QTAIM) and natural bond orbital analysis. It was observed that the strength of these bonds is directly correlated with the relative stability of isomers involved in nitro-nitrito and nitrosyl-isonitrosyl isomerism, as described previously by Coppens and Ooyama.
Authors:
Karla Furtado Andriani; Giovanni Finoto Caramori; Fábio Gorzoni Doro; Renato Luis Tame Parreira
Related Documents :
22029227 - Sesquiterpene lactone, a potent drug molecule from artemisia pallens wall with anti-inf...
20372747 - Activation and cleavage of the n-n bond in side-on bound [l₂m-nn-ml₂] (l = nh₂, nme₂, n...
8769337 - Distribution of cobalt chromium wear and corrosion products and biologic reactions.
24187977 - Modulation of electronics and thermal stabilities of photochromic phosphino-aminoazoben...
21582657 - Bis(acetato-κo)bis-(μ(3)-quinolin-8-olato-κn,o:o:o)tetra-kis(μ(2)-quinolin-8-olato-κn,o...
17256867 - Bis(2-pyridyl)-substituted boratriazaindacene as an nir-emitting chemosensor for hg(ii).
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2014-4-29
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2014 Apr 
Date Detail:
Created Date:  2014-4-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  The short-chain fatty acid acetate reduces appetite via a central homeostatic mechanism.
Next Document:  Lack of association between peri-procedural myocardial damage and CYP2C19 gene variant in elective p...