Document Detail


Routine use of natural abundance deuterium NMR in a polypeptidic chiral oriented solvent for the determination of the enantiomeric composition of chiral building blocks.
MedLine Citation:
PMID:  12000268     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
[reaction: see text] Natural abundance deuterium 2D NMR spectroscopy in chiral liquid crystal was successfully used to efficiently analyze the enantiomeric composition of organic chiral building blocks involved in the syntheses of natural and synthetic bioactive products. The results reported here emphasize the high potential of this analytical strategy and prove its applicability for routinely determining enantiomeric excesses.
Authors:
Arnaud Parenty; Jean-Marc Campagne; Christie Aroulanda; Philippe Lesot
Related Documents :
19007478 - Preparation and chiral recognition of a mono[6a-n-1-(2-hydroxy)-phenylethylimino-6a-deo...
22862678 - Highly luminescent and thermally stable lanthanide coordination polymers designed from ...
11126298 - Parallel solid-phase synthesis and structural characterization of a library of highly s...
20867548 - Chiral symmetry breaking in crystals of achiral polymers.
17596898 - Assessment of the microsurgical skills: 30 minutes versus 2 weeks patency.
11666258 - Two new antiferromagnetic nickel(ii) complexes bridged by azido ligands in the cis posi...
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Organic letters     Volume:  4     ISSN:  1523-7060     ISO Abbreviation:  Org. Lett.     Publication Date:  2002 May 
Date Detail:
Created Date:  2002-05-09     Completed Date:  2002-07-01     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  1663-6     Citation Subset:  IM    
Affiliation:
ICSN-CNRS, Avenue de la Terrasse, 91198 Gif sur Yvette, France.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:
Deuterium / chemistry
Indicators and Reagents
Magnetic Resonance Spectroscopy
Peptides / chemistry*
Solvents
Chemical
Reg. No./Substance:
0/Indicators and Reagents; 0/Peptides; 0/Solvents; 7782-39-0/Deuterium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Selective ruthenium-catalyzed oxidation of 1,2:4,5-di-O-isopropylidene- beta-D-fructopyranose and ot...
Next Document:  Self-assembly of molecular capsules in polar solvents.