Document Detail


Room-temperature luminescence analysis of drugs with application to the Toxi-Lab drug identification system.
MedLine Citation:
PMID:  3573728     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A method of analyzing drugs on the Toxi-Lab thin-layer chromatographic system by solid substrate room-temperature luminescence is described. Three pairs of unresolved drugs: quinine/cimetidine, caffeine/chlordiazepoxide, and phenazopyridine/lidocaine, were studied as model compounds. Their luminescence characteristics were obtained and calibration curves were found to be linear over two orders of magnitude. The effect of the nonluminescent component of each pair on the determination of the luminescent component was found to be negligible. Statistical F-tests showed that the observed differences in the slopes and intercepts of the calibration curves were due to random errors. The method was evaluated by determining quinine in urine samples at the ng level.
Authors:
E B Asafu-Adjaye; S Y Su; H T Karnes
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of analytical toxicology     Volume:  11     ISSN:  0146-4760     ISO Abbreviation:  J Anal Toxicol     Publication Date:    1987 Mar-Apr
Date Detail:
Created Date:  1987-06-17     Completed Date:  1987-06-17     Revised Date:  2004-11-17    
Medline Journal Info:
Nlm Unique ID:  7705085     Medline TA:  J Anal Toxicol     Country:  UNITED STATES    
Other Details:
Languages:  eng     Pagination:  70-4     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Caffeine / analysis
Calibration
Chlordiazepoxide / analysis
Chromatography, Thin Layer / methods*
Cimetidine / analysis
Lidocaine / analysis
Luminescent Measurements
Pharmaceutical Preparations / analysis*
Phenazopyridine / analysis
Quinine / analysis
Chemical
Reg. No./Substance:
0/Pharmaceutical Preparations; 130-95-0/Quinine; 137-58-6/Lidocaine; 51481-61-9/Cimetidine; 58-08-2/Caffeine; 58-25-3/Chlordiazepoxide; 94-78-0/Phenazopyridine

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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