| Room temperature dynamic polymers based on Diels-Alder chemistry. | |
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MedLine Citation:
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PMID: 19132706 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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Dynamers based on reversible Diels-Alder chemistry have been obtained and shown to undergo dynamic exchange at room temperature. Their study in solution by small-angle neutron scattering indicated the formation of long and highly flexible chains. Polydispersed molecules gave T(g) values below room temperature, permitting the generation of a dynamic elastomer upon introduction of a dynamic cross-linking agent. The use of a system with a low equilibrium constant gives access to materials with interesting self-healing properties. |
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Authors:
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P Reutenauer; E Buhler; P J Boul; S J Candau; J-M Lehn |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Chemistry (Weinheim an der Bergstrasse, Germany) Volume: 15 ISSN: 1521-3765 ISO Abbreviation: Chemistry Publication Date: 2009 |
Date Detail:
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Created Date: 2009-02-09 Completed Date: 2009-02-17 Revised Date: 2009-08-04 |
Medline Journal Info:
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Nlm Unique ID: 9513783 Medline TA: Chemistry Country: Germany |
Other Details:
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Languages: eng Pagination: 1893-900 Citation Subset: - |
Affiliation:
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Laboratoire de Chimie Supramoléculaire, ISIS, Université de Strasbourg, 8 allée Gaspard Monge, 67000 Strasbourg, France. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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