Document Detail


Room temperature palladium-catalyzed decarboxylative ortho-acylation of acetanilides with alpha-oxocarboxylic acids.
MedLine Citation:
PMID:  20698536     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A novel Pd-catalyzed decarboxylative ortho-acylation of acetanilides with alpha-oxocarboxylic acids is realized at room temperature. This reaction provides efficient access to o-acyl acetanilides under mild conditions.
Authors:
Ping Fang; Mingzong Li; Haibo Ge
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.    
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  132     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2010 Sep 
Date Detail:
Created Date:  2010-08-25     Completed Date:  2010-12-08     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  11898-9     Citation Subset:  IM    
Affiliation:
Department of Chemistry and Chemical Biology, Indiana University Purdue University Indianapolis, Indianapolis, Indiana 46202, USA.
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MeSH Terms
Descriptor/Qualifier:
Acetanilides / chemistry*
Carboxylic Acids / chemistry*
Catalysis
Decarboxylation
Ketones / chemical synthesis*,  chemistry
Molecular Structure
Organometallic Compounds / chemistry*
Palladium / chemistry*
Stereoisomerism
Temperature*
Chemical
Reg. No./Substance:
0/Acetanilides; 0/Carboxylic Acids; 0/Ketones; 0/Organometallic Compounds; 7440-05-3/Palladium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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