| Room temperature palladium-catalyzed decarboxylative ortho-acylation of acetanilides with alpha-oxocarboxylic acids. | |
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MedLine Citation:
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PMID: 20698536 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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A novel Pd-catalyzed decarboxylative ortho-acylation of acetanilides with alpha-oxocarboxylic acids is realized at room temperature. This reaction provides efficient access to o-acyl acetanilides under mild conditions. |
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Authors:
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Ping Fang; Mingzong Li; Haibo Ge |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S. |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: 132 ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2010 Sep |
Date Detail:
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Created Date: 2010-08-25 Completed Date: 2010-12-08 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: United States |
Other Details:
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Languages: eng Pagination: 11898-9 Citation Subset: IM |
Affiliation:
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Department of Chemistry and Chemical Biology, Indiana University Purdue University Indianapolis, Indianapolis, Indiana 46202, USA. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Acetanilides
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chemistry* Carboxylic Acids / chemistry* Catalysis Decarboxylation Ketones / chemical synthesis*, chemistry Molecular Structure Organometallic Compounds / chemistry* Palladium / chemistry* Stereoisomerism Temperature* |
| Chemical | |
Reg. No./Substance:
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0/Acetanilides; 0/Carboxylic Acids; 0/Ketones; 0/Organometallic Compounds; 7440-05-3/Palladium |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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