Document Detail


Ring opening vs. direct bond scission of the chain in polymeric triazoles under the influence of an external force.
MedLine Citation:
PMID:  22991689     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Density functional theory calculations show that both ring opening and chain dissociation of polymeric triazoles are facilitated by mechanical stretching of the molecules-the latter more than the former. Experimentally observed ring opening upon sonication can therefore not be explained by a mechanical stretching mechanism alone.
Authors:
Hans S Smalø; Einar Uggerud
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-19
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-19     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway. einar.uggerud@kjemi.uio.no.
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