| Rigid crosslinked polyacrylamide monoliths with well-defined macropores synthesized by living polymerization. | |
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MedLine Citation:
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PMID: 21706559 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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Rigid crosslinked polyacrylamide monoliths with well-defined macropores have been successfully fabricated by organotellurium-mediated living radical polymerization (TERP) accompanied by spinodal decomposition. The TERP forms homogeneous networks derived from N,N-methylenebis(acrylamide) (BIS), in which spinodal decomposition is induced to form macropores. Macropore diameter can be controlled from submicrons to a few microns, and also the obtained networks contain mesopores in the macroporous skeletons, which are collapsed by evaporative drying. They are promising materials with hydrophilic polyacrylamide surfaces and have enough strength to preserve the macropores from the surface tension arising in the repetitive swelling and drying that may occur in many applications. |
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Authors:
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Joji Hasegawa; Kazuyoshi Kanamori; Kazuki Nakanishi; Teiichi Hanada; Shigeru Yamago |
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Publication Detail:
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Type: Journal Article Date: 2009-04-01 |
Journal Detail:
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Title: Macromolecular rapid communications Volume: 30 ISSN: 1022-1336 ISO Abbreviation: Macromol Rapid Commun Publication Date: 2009 Jun |
Date Detail:
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Created Date: 2011-06-27 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9888239 Medline TA: Macromol Rapid Commun Country: Germany |
Other Details:
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Languages: eng Pagination: 986-90 Citation Subset: - |
Copyright Information:
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Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, Japan. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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