| Rhodium-catalyzed enantioselective 1,6-addition of arylboronic acids to enynamides: asymmetric synthesis of axially chiral allenylsilanes. | |
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MedLine Citation:
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PMID: 20806919 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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Rhodium-catalyzed asymmetric 1,6-addition of arylboronic acids to β-alkynyl acrylamides substituted with a silyl group on the alkyne terminus took place to give high yields of axially chiral allenylsilanes with 94-99% enantioselectivity, which was realized by use of a rhodium/chiral diene complex. |
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Authors:
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Takahiro Nishimura; Hiroki Makino; Makoto Nagaosa; Tamio Hayashi |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: 132 ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2010 Sep |
Date Detail:
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Created Date: 2010-09-15 Completed Date: 2011-01-04 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: United States |
Other Details:
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Languages: eng Pagination: 12865-7 Citation Subset: - |
Affiliation:
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Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan. tnishi@kuchem.kyoto-u.ac.jp |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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