Document Detail

Reversible aryl migrations in metallated ureas: controlled inversion of configuration at a quaternary carbon atom.
MedLine Citation:
PMID:  23324729     Owner:  NLM     Status:  Publisher    
Deprotonation with strong bases of N-vinyl ureas carrying an N'-aryl substituent leads to migration of the N'-aryl group from N to C via an allyllithium; with weaker bases and electron-deficient aryl rings the direction of the migration reverses, and aryl substituents α to the urea N atom may migrate from C to N.
Daniel J Tetlow; Mark A Vincent; Ian H Hillier; Jonathan Clayden
Related Documents :
16578739 - Maximally dependent random variables.
18472749 - Metallation of isatin (2,3-indolinedione). x-ray structure and solution behavior of bis...
18007399 - Synthesis and characterization of dimethacrylate monomer with high molecular weight for...
17828719 - Synthesis and characterization of acetylene-linked bisphenalenyl and metallic-like beha...
11670219 - Luminescent and redox-active iridium(iii)-cyclometalated compounds with terdentate liga...
23646559 - Effective photoluminescence in a large-area array of ta2o5 nanodots.
21582259 - 4-(4-methoxy-phen-yl)-4-methyl-2,6-diphenyl-4h-thio-pyran.
19002399 - Influence of micro-organisms on the dissolution of metallic platinum emitted by automob...
22814869 - New bis(aryloxy)-ti(iv) complexes and their use for the selective dimerization of ethyl...
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-17
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-17     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

Previous Document:  Job stress dimensions and their relationship to musculoskeletal disorders in Iranian nurses.
Next Document:  Geometry-induced spin-ice structures prepared by self-organization on the nanoscale.