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Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters.
MedLine Citation:
PMID:  23355424     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Catalyst tune-up: A readily available, air-stable amino-sulfide catalyst, [RuCl(2) (PPh(3) ){HN(C(2) H(4) SEt)(2) }], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with CX bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling of ethanol to ethyl acetate.
Authors:
Denis Spasyuk; Samantha Smith; Dmitry G Gusev
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-28
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-28     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Chemistry, Wilfrid Laurier University, 75 University Ave. W., Waterloo, ON N2L3C5 (Canada) http://wlu.ca/homepage.php?grp_id=366.
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