Document Detail

Removal of phosphate from water using six Al-, Fe-, and Al-Fe-modified bentonite adsorbents.
MedLine Citation:
PMID:  23043345     Owner:  NLM     Status:  In-Data-Review    
This study was part of a larger effort that involves evaluating alternatives to upgrading secondary treatment systems in the United Arab Emirates for the removal of nutrients. In this study, six modified bentonite (BNT) phosphate adsorbents were prepared using solutions that contained hydroxy-polycations of aluminum (Al-BNT), iron (Fe-BNT), and mixtures of aluminum and iron (Al-Fe-BNT). The adsorption kinetics and capacities of the six adsorbents were evaluated, and the adsorbents were used to remove phosphorus from synthetic phosphate solutions and from treated wastewater. The experimental adsorption kinetics results were well represented by the pseudo-second-order kinetic model, with R(2) values ranging from 0.99 to 1.00. Similarly, the experimental equilibrium adsorption results were well represented by the Freundlich and Langmuir isotherms, with R(2) values ranging from 0.98 to 1.00. The adsorption capacities of the adsorbents were dependent on the BNT preparation conditions; the types, quantities and combination of metals used; BNT particle size; and adsorption pH. The Langmuir maximum adsorption capacities of the six adsorbents ranged from 8.9-14.5 mg P/g-BNT. The results suggested that the BNT preparations containing Fe alone or in combination with Al achieved higher adsorption capacities than the preparations containing only Al. However, the Al-BNT preparations exhibited higher adsorption rates than the Fe-BNT preparation. Three of the six adsorbents were used to remove phosphate from secondarily treated wastewater samples, and the removal results were comparable to those obtained using synthetic phosphate solutions. The BNT adsorbents also exhibited adequate settling characteristics and significant regeneration potential.
Abdallah M Shanableh; Moetaz M Elsergany
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering     Volume:  48     ISSN:  1532-4117     ISO Abbreviation:  J Environ Sci Health A Tox Hazard Subst Environ Eng     Publication Date:  2013  
Date Detail:
Created Date:  2012-10-09     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9812551     Medline TA:  J Environ Sci Health A Tox Hazard Subst Environ Eng     Country:  England    
Other Details:
Languages:  eng     Pagination:  223-31     Citation Subset:  IM    
a Department of Civil and Environmental Engineering , University of Sharjah, United Arab Emirates.
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