Document Detail

Regioselective CH Alkylation of Anisoles with Olefins Catalyzed by Cationic Half-Sandwich Rare Earth Alkyl Complexes.
MedLine Citation:
PMID:  23135839     Owner:  NLM     Status:  Publisher    
A half sandwich helping: Cationic rare-earth alkyl species generated from half-sandwich rare-earth dialkyl complexes and [Ph(3) C][B(C(6) F(5) )(4) ] can serve as unique catalysts for the CH regioselective alkylation of anisoles with alkenes. The reaction affords either ortho-monoalkylated derivatives or products substituted at the benzylic position, depending on the substrate chosen.
Juzo Oyamada; Zhaomin Hou
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-7
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Organometallic Chemistry Laboratory and Advanced Catalyst Research Team, RIKEN Advanced Science Institute, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan).
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