Document Detail


Regioselective CH Alkylation of Anisoles with Olefins Catalyzed by Cationic Half-Sandwich Rare Earth Alkyl Complexes.
MedLine Citation:
PMID:  23135839     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A half sandwich helping: Cationic rare-earth alkyl species generated from half-sandwich rare-earth dialkyl complexes and [Ph(3) C][B(C(6) F(5) )(4) ] can serve as unique catalysts for the CH regioselective alkylation of anisoles with alkenes. The reaction affords either ortho-monoalkylated derivatives or products substituted at the benzylic position, depending on the substrate chosen.
Authors:
Juzo Oyamada; Zhaomin Hou
Related Documents :
23011639 - Catalytic selective synthesis.
20693069 - Prediction of drug-induced immediate hypersensitivity in guinea pigs.
24490119 - Cyanobacterial aldehyde deformylase oxygenation of aldehydes yields n-1 aldehydes and a...
24425679 - Transition metal mediated [(11) c]carbonylation reactions: recent advances and applicat...
22062139 - Volatile compounds of dry-cured iberian ham as affected by the length of the curing pro...
24115199 - Organic chemistry of graphene: the diels-alder reaction.
24061259 - Synthesis and characterization of binol based axially chiral nitronyl nitroxide radicals.
8365489 - Peroxynitrite modification of low-density lipoprotein leads to recognition by the macro...
21283559 - Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced ...
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-7
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Organometallic Chemistry Laboratory and Advanced Catalyst Research Team, RIKEN Advanced Science Institute, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan).
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Investigation of the Substrate Range of CYP199A4: Modification of the Partition between Hydroxylatio...
Next Document:  Rice artificial hybridization for genetic analysis.