Document Detail

Regiocontrolled addition of arylboronic acids to allenes using palladium and platinum catalysts.
MedLine Citation:
PMID:  18939800     Owner:  NLM     Status:  MEDLINE    
Studies about the regiocontrolled addition of arylboronic acids to allenes using a palladium or a platinum catalyst have been described. The selectivity of the reaction can be altered by the choice of the metal reagent and base. Contrary to the formation of endo-olefinic products in the reactions using hydroxopalladium complex, predominant production of exo-olefinic products was observed by the reaction with hydroxoplatinum complex.
Masahiro Yoshida; Kennosuke Matsuda; Yasunobu Shoji; Takahiro Gotou; Masataka Ihara; Kozo Shishido
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2008-10-22
Journal Detail:
Title:  Organic letters     Volume:  10     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2008 Nov 
Date Detail:
Created Date:  2008-11-17     Completed Date:  2008-12-15     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  5183-6     Citation Subset:  IM    
Graduate School of Pharmaceutical Sciences, The University of Tokushima, Tokushima, Japan.
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MeSH Terms
Alkadienes / chemistry*
Boronic Acids / chemistry*
Palladium / chemistry*
Platinum / chemistry*
Reg. No./Substance:
0/Alkadienes; 0/Boronic Acids; 463-49-0/propadiene; 7440-05-3/Palladium; 7440-06-4/Platinum

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