| Refined model of optical activity of cis-dihydrodiol metabolites: role of 1,3-diene conformation in the electronic circular dichroism spectra. | |
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MedLine Citation:
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PMID: 22135803 Owner: NLM Status: In-Process |
Abstract/OtherAbstract:
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The effect of the secondary structural feature, that is, nonplanarity of carbon-carbon double bonds, on the rotatory strength of the long-wavelength π-π* electronic transition has been investigated for the series of monocyclic cis-dihydrodiol arene metabolites and model compounds. The contribution from nonplanar C=C bonds to the overall rotatory strength of the π-π* electronic transition is more significant than the contribution from twisted 1,3-diene chromophore. The effect of the substitution pattern in the cyclohexadiene skeleton may be decisive for the sign of the long-wavelength π-π* Cotton effect. |
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Authors:
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Marcin Kwit; Jacek Gawronski |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Chirality Volume: 23 ISSN: 1520-636X ISO Abbreviation: Chirality Publication Date: 2011 Oct |
Date Detail:
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Created Date: 2011-12-01 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 8914261 Medline TA: Chirality Country: United States |
Other Details:
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Languages: eng Pagination: 744-51 Citation Subset: IM |
Copyright Information:
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© 2011 Wiley-Liss, Inc. |
Affiliation:
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Department of Chemistry, A. Mickiewicz University, Poznan 60-780, Poland. Marcin.Kwit@amu.edu.pl |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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