| Reduction of metal ions by boranephosphonate DNA. | |
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MedLine Citation:
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PMID: 23032580 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Oligodeoxyribonucleotides bearing boranephosphonate linkages (bpDNA) were shown to reduce a number of metal ions and form nanoparticles through a novel reaction pathway that leads to phosphate diesters or phosphate triesters in water or alcohols respectively. The synthetic utility of this reaction was further demonstrated through the synthesis of oligodeoxyribonucleotides containing phosphate triester linkages. This new reactivity also makes bpDNA promising for use in construction of DNA templated metallic nanostructures. |
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Authors:
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Subhadeep Roy; Magdalena Olesiak; Petra Padar; Heather McCuen; Marvin H Caruthers |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-3 |
Journal Detail:
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Title: Organic & biomolecular chemistry Volume: - ISSN: 1477-0539 ISO Abbreviation: Org. Biomol. Chem. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-3 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101154995 Medline TA: Org Biomol Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry and Biochemistry, University of Colorado, 3415 Colorado Ave., JSC Biotech Bldg. 530, UCB 596, Boulder, CO 80309, USA. marvin.caruthers@colorado.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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