Document Detail


Reduction of metal ions by boranephosphonate DNA.
MedLine Citation:
PMID:  23032580     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Oligodeoxyribonucleotides bearing boranephosphonate linkages (bpDNA) were shown to reduce a number of metal ions and form nanoparticles through a novel reaction pathway that leads to phosphate diesters or phosphate triesters in water or alcohols respectively. The synthetic utility of this reaction was further demonstrated through the synthesis of oligodeoxyribonucleotides containing phosphate triester linkages. This new reactivity also makes bpDNA promising for use in construction of DNA templated metallic nanostructures.
Authors:
Subhadeep Roy; Magdalena Olesiak; Petra Padar; Heather McCuen; Marvin H Caruthers
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-3
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  -     ISSN:  1477-0539     ISO Abbreviation:  Org. Biomol. Chem.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry and Biochemistry, University of Colorado, 3415 Colorado Ave., JSC Biotech Bldg. 530, UCB 596, Boulder, CO 80309, USA. marvin.caruthers@colorado.edu.
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