Document Detail


Reduced iron induced nitric oxide and nitrous oxide emission.
MedLine Citation:
PMID:  21940030     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Formation of the greenhouse gas nitrous oxide in water treatment systems is predominantly studied as a biological phenomenon. There are indications that also chemical processes contribute to these emissions. Here we studied the formation of nitric oxide (NO) and nitrous oxide (N(2)O) due to chemical nitrite reduction by ferrous iron (Fe(II)). Reduction of nitrite and NO coupled to Fe(II) oxidation was studied in laboratory-scale chemical experiments at different pH, nitrite and iron concentrations. The continuous measurement of both NO and N(2)O emission showed that nitrite reduction and NO reduction have different kinetics. Nitrite reduction shows a linear dependency on the nitrite concentration, implying first order kinetics in nitrite. The nitrite reduction seems to be an equilibrium based reaction, leading to a constant NO concentration in the liquid. The NO reduction rate is suggested to be most dependent on reactive surface availability and the sorption of Fe(II) to the reactive surface. The importance of emission of NO and N(2)O coupled to iron oxidation is exemplified by iron reduction experiments and several examples of environments where this pathway can play a role.
Authors:
Marlies J Kampschreur; Robbert Kleerebezem; Weren W J M de Vet; Mark C M van Loosdrecht
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-9-12
Journal Detail:
Title:  Water research     Volume:  -     ISSN:  1879-2448     ISO Abbreviation:  -     Publication Date:  2011 Sep 
Date Detail:
Created Date:  2011-9-23     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0105072     Medline TA:  Water Res     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2011 Elsevier Ltd. All rights reserved.
Affiliation:
Delft University of Technology, Department of Biotechnology, Delft, The Netherlands.
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