Document Detail


Recovery of fluorine from bastnasite as synthetic cryolite by-product.
MedLine Citation:
PMID:  22281026     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
This paper investigates the development of a new environment friendly approach for treatment of bastnasite. A new process was developed to recover fluorine from bastnasite as synthetic cryolite by-product. The conditions affecting the fluorine removal and recovery in the process, including contact time, acidity, Al(3+) concentration, Al/F molar ratio and different kinds of aluminum salts being used, were investigated. The results indicate that high acidity and large Al/F molar ratio were beneficial to fluoride removal, and that the reaction reached equilibrium after 15min. The effect of the initial Al(3+) concentration at a certain total Al(3+) amount was slight. Aluminum nitrate was more efficient than aluminum sulfate for the removal of fluoride. Optimum operation parameters for synthesizing cryolite have been obtained and proposed for industrial applications.
Authors:
Liangshi Wang; Chunmei Wang; Ying Yu; Xiaowei Huang; Zhiqi Long; Yongke Hou; Dali Cui
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-1-10
Journal Detail:
Title:  Journal of hazardous materials     Volume:  -     ISSN:  1873-3336     ISO Abbreviation:  -     Publication Date:  2012 Jan 
Date Detail:
Created Date:  2012-1-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9422688     Medline TA:  J Hazard Mater     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 Elsevier B.V. All rights reserved.
Affiliation:
National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals, and Grirem Advanced Materials Co. Ltd., Beijing 100088, PR China.
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