Document Detail


Rearrangement from the heteroantiaromatic borole to the heteroaromatic azaborine motif.
MedLine Citation:
PMID:  22465974     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Treatment of 9-chloro-9-borafluorene with N,O-bis(trimethylsilyl)hydroxylamine results in 10-trimethylsilyloxy-9-aza-10-boraphenanthrene . NMR spectroscopy shows that the expected antiaromatic 9-(trimethylsilyloxyamino)-9-borafluorene rearranges to the formally aromatic phenanthrene at room temperature.
Authors:
Sunanda Biswas; Cäcilia Maichle-Mössmer; Holger F Bettinger
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-3-30
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  -     Publication Date:  2012 Mar 
Date Detail:
Created Date:  2012-4-2     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany. holger.bettinger@uni-tuebingen.de.
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