| Rearrangement strategy for the synthesis of 2-aminoanilines. | |
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MedLine Citation:
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PMID: 20199033 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Treatment of N-aryl hydroxylamines with trichloroacetonitrile in the presence of imidazole provides a simple and effective method for the preparation of synthetically versatile 2-aminoanilines. Reactions proceed in DMF at 40 degrees C, providing the products in up to 86% isolated yield. |
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Authors:
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Achim Porzelle; Michael D Woodrow; Nicholas C O Tomkinson |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Organic letters Volume: 12 ISSN: 1523-7052 ISO Abbreviation: Org. Lett. Publication Date: 2010 Apr |
Date Detail:
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Created Date: 2010-03-26 Completed Date: 2010-06-24 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 1492-5 Citation Subset: IM |
Affiliation:
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School of Chemistry, Main Building, Cardiff University, Park Place, Cardiff, CF10 3AT, UK. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Aniline Compounds
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chemical synthesis*,
chemistry Molecular Structure Stereoisomerism |
| Chemical | |
Reg. No./Substance:
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0/Aniline Compounds |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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