Document Detail

Reactions of a tungsten-germylyne complex with alcohols and arylaldehydes.
MedLine Citation:
PMID:  23149470     Owner:  NLM     Status:  Publisher    
A germylyne complex Cp*(CO)(2)W[triple bond, length as m-dash]GeC(SiMe(3))(3) () reacted with alcohols to give simple nucleophilic addition products, while reacted with two molecules of arylaldehydes consecutively to give base-stabilised alkoxy(germylene) complexes via C-H bond activation and hydrogermylation.
Tetsuya Fukuda; Hisako Hashimoto; Hiromi Tobita
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-14
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai, 980-8578, Japan.
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