Document Detail

Rapid separation of triacylglycerol positional isomers binding two saturated Fatty acids using octacocyl silylation column.
MedLine Citation:
PMID:  21701097     Owner:  NLM     Status:  In-Data-Review    
The rapid separation of a triacylglycerol positional isomer (TAG-PI) pair was examined via high-performance liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry using an octacocyl silylation (C28) column. A TAG-PI pair binding two palmitic acids and one fatty acid that structurally differs from palmitic acid was separated at 10°C and 15°C using acetone as the mobile phase. However, the TAG-PI pair binding two unsaturated fatty acids and one saturated fatty acid was not separated by the C28 column. The results indicate that the structures of the two palmitic acids (saturated fatty acids) and the other fatty acid at the α or β position in TAG play an important role in the separation of the TAG-PI pair, and that the structure of the fatty acid needs to be considerably different from that of the palmitic acid, specifically in terms of the chain length or the location of the double bond.
Toshiharu Nagai; Naohiro Gotoh; Hoyo Mizobe; Kazuaki Yoshinaga; Koichi Kojima; Yumiko Matsumoto; Shun Wada
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of oleo science     Volume:  60     ISSN:  1347-3352     ISO Abbreviation:  J Oleo Sci     Publication Date:  2011  
Date Detail:
Created Date:  2011-06-24     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101175339     Medline TA:  J Oleo Sci     Country:  Japan    
Other Details:
Languages:  eng     Pagination:  345-50     Citation Subset:  IM    
Tsukishima Foods Industry Co., Ltd.
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