Document Detail


Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO(2).
MedLine Citation:
PMID:  23321598     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Flowing supercritical CO(2) was used to activate a cross section of microporous coordination polymers (MCPs) directly from DMF, thus avoiding exchange with a volatile solvent. Most MCPs displayed exceptional surface areas directly after treatment although those with coordinatively unsaturated metals benefit from heating. The method presents an advance in efficiency of activation and quality of material obtained.
Authors:
Baojian Liu; Antek G Wong-Foy; Adam J Matzger
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-16
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
School of Biological and Chemical Engineering, Zhejiang University of Science and Technology, 318 Liuhe Road, Hangzhou, Zhejiang 310023, China.
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