Document Detail


Radially oriented anthracene nanowire arrays: preparation, growth mechanism, and optical fluorescence.
MedLine Citation:
PMID:  21380477     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Radially oriented anthracene nanowires and their self-assembled concentric ring arrays were prepared through a facial solvent-evaporation method. The successful growth of anthracene nanowires can be attributed to a combined mechanism of molecular self-assembly facilitated by strong π-π intermolecular interactions together with evaporation-induced capillary flow and fingering instability. Their radial orientation is determined by the capillary flow; their shape (either straight or curved nanowires) is governed by the competition between the capillary and Marangoni convectional flows. The self-assembly of nanowires into large-scale concentric ring arrays can be interpreted in terms of the repeated slipping-and-sticking motions of the contact line. The high-quality crystalline anthracene nanowire arrays exhibit size-dependent fluorescence emission with high-degree anisotropy.
Authors:
Ji Hong Wu; Tian Ze Xu; Siau Gek Ang; Qing-Hua Xu; Guo Qin Xu
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-3-7
Journal Detail:
Title:  Nanoscale     Volume:  -     ISSN:  2040-3372     ISO Abbreviation:  -     Publication Date:  2011 Mar 
Date Detail:
Created Date:  2011-3-7     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101525249     Medline TA:  Nanoscale     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Republic of Singapore117543. chmxugq@nus.edu.sg chmxqh@nus.edu.sg.
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