Document Detail


Quantitation of the epsilon-(gamma-glutamyl)lysine cross-link using a high-speed amino acid analyzer without purification of the dipeptide. Application to enzymatic digested mixtures of keratin and the membranous fraction of human stratum corneum.
MedLine Citation:
PMID:  6192134     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
epsilon-(gamma-Glutamyl)lysine in an enzymically digested mixture of keratin and the membranous fraction of human stratum corneum was directly quantitated using a high-speed amino acid analyzer without purification of the dipeptide. The analytical conditions were improved so that epsilon-(gamma-glutamyl)lysine clearly separated from other amino acids and eluted directly after tyrosine. The enzymatically digested mixtures were filtered through an Ultra Free membrane and deammoniated before analysis. By our present method, keratin and the membranous fraction of human stratum corneum were analyzed and 5.8 and 43.5 nmol/mg of epsilon-(gamma-glutamyl)lysine, respectively, were detected.
Authors:
K Murayama; T Sugawara; E Hiraga; H Ogawa
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of chromatography     Volume:  274     ISSN:  0021-9673     ISO Abbreviation:  J. Chromatogr.     Publication Date:  1983 May 
Date Detail:
Created Date:  1983-09-09     Completed Date:  1983-09-09     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0427043     Medline TA:  J Chromatogr     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  63-73     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Amino Acids / analysis
Autoanalysis / methods
Chromatography, Ion Exchange
Dipeptides / isolation & purification*
Enzymes
Humans
Keratins / analysis*
Methods
Skin / analysis*
Chemical
Reg. No./Substance:
0/Amino Acids; 0/Dipeptides; 0/Enzymes; 17105-15-6/epsilon-(gamma-glutamyl)-lysine; 68238-35-7/Keratins

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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