Document Detail


Quantification of urinary F2-isoprostanes with 4(RS)-F4t-neuroprostane as an internal standard using gas chromatography-mass spectrometry Application to polytraumatized patients.
MedLine Citation:
PMID:  18706873     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Isoprostanes are a family of prostaglandin isomers produced from oxidation of polyunsaturated fatty acids through a non-enzymatic free radical-catalyzed mechanism. Quantification of F(2)-isoprostanes (F(2)-IsoPs) provides a good index of oxidative stress and allows non-invasive assessment of lipid peroxidation in vivo. Since "interferences peaks" at m/z 573 co-elute with d(4)-15-F(2t)-IsoP preferentially used, we propose a new GC-NICI-MS approach to quantify urinary F(2)-IsoPs by using 4(RS)-F(4t)-neuroprostane as the internal standard. This method was applied to quantify urinary F(2)-IsoPs excretion in healthy volunteers and polytraumatized patients. Our results showed a significant increase (p<0.0001) in urinary F(2)-IsoPs in polytraumatized patients compared with healthy volunteers (4.73+/-2.75 ng/mg vs. 0.811+/-0.359 ng/mg creatinine).
Authors:
Emilie Mas; Françoise Michel; Alexandre Guy; Valérie Bultel; Yoan Falquet; Patrick Chardon; Jean-Claude Rossi; Jean Paul Cristol; Thierry Durand
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Publication Detail:
Type:  Journal Article     Date:  2008-08-03
Journal Detail:
Title:  Journal of chromatography. B, Analytical technologies in the biomedical and life sciences     Volume:  872     ISSN:  1570-0232     ISO Abbreviation:  J. Chromatogr. B Analyt. Technol. Biomed. Life Sci.     Publication Date:  2008 Sep 
Date Detail:
Created Date:  2008-08-26     Completed Date:  2008-10-28     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101139554     Medline TA:  J Chromatogr B Analyt Technol Biomed Life Sci     Country:  Netherlands    
Other Details:
Languages:  eng     Pagination:  133-40     Citation Subset:  IM    
Affiliation:
Department of Biochemistry, Lapeyronie Hospital, Montpellier, France.
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MeSH Terms
Descriptor/Qualifier:
Case-Control Studies
F2-Isoprostanes / urine*
Gas Chromatography-Mass Spectrometry / methods*
Humans
Lipid Peroxidation
Multiple Trauma / urine*
Reference Standards
Reproducibility of Results
Chemical
Reg. No./Substance:
0/F2-Isoprostanes

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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