Document Detail


Quantification of spiroether isomers and herniarin of different parts of Matricaria matricarioides and flowers of Chamaemelum nobile.
MedLine Citation:
PMID:  17260697     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A simple HPLC-PAD-MS method was established to quantitatively analyse two spiroether isomers (cis-en-yn-dicycloether and trans-en-yn-dicycloether) and the main coumarin, herniarin, in chamomile herbs, simultaneously. By using this method, the contents of these three compounds in the flowers of two chamomile species, Roman chamomile (Chamaemelum nobile) and pineapple weed (Matricaria matricarioides), as well as in different parts of pineapple weed, were investigated. It was found that the flowers of both herbs contained large amounts of cis-en-yn-dicycloether and trans-en-yn-dicycloether, with the trans-form being more abundant than the cis-form. The leaves of pineapple weed were found to have the highest concentration of cis-en-yn-dicycloether and herniarin than the other parts. HPLC-PAD-MS-guided isolation and identification of other constituents are also discussed.
Authors:
Chao-Mei Ma; Linda Winsor; Mohsen Daneshtalab
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Phytochemical analysis : PCA     Volume:  18     ISSN:  0958-0344     ISO Abbreviation:  Phytochem Anal     Publication Date:    2007 Jan-Feb
Date Detail:
Created Date:  2007-01-30     Completed Date:  2007-02-13     Revised Date:  2012-12-10    
Medline Journal Info:
Nlm Unique ID:  9200492     Medline TA:  Phytochem Anal     Country:  England    
Other Details:
Languages:  eng     Pagination:  42-9     Citation Subset:  IM    
Affiliation:
School of Pharmacy, Memorial University of Newfoundland, St. John's, Newfoundland and Labrador, Canada A1B 3V6.
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MeSH Terms
Descriptor/Qualifier:
Calibration
Chamaemelum / chemistry*
Chromatography, High Pressure Liquid
Flowers / chemistry*
Isomerism
Matricaria / chemistry*
Plant Leaves / chemistry
Quality Control
Reference Standards
Reproducibility of Results
Spectrometry, Mass, Electrospray Ionization
Spectrophotometry, Ultraviolet
Umbelliferones / analysis*,  isolation & purification
Chemical
Reg. No./Substance:
0/Umbelliferones; 531-59-9/herniarin

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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