Document Detail


Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex.
MedLine Citation:
PMID:  23685618     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We herein report the synthesis of a bis-2-pyridylidene palladium(ii) complex as an isoelectronic structure of the well-known 2,2'-bipyridine complexes. One-pot or stepwise C-Cl oxidative addition followed by base-mediated C-H palladation of the chlorobipyridine dication to palladium(0) yielded the bis-2-pyridylidene palladium(ii) carbonate smoothly.
Authors:
Tetsushi Yoshidomi; Yasutomo Segawa; Kenichiro Itami
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-5-17
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 May 
Date Detail:
Created Date:  2013-5-20     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. ysegawa@nagoya-u.jp.
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