Document Detail


Protochlorophyllide b does not occur in barley etioplasts.
MedLine Citation:
PMID:  10094504     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Barley (Hordeum vulgare L.) etioplasts were isolated, and the pigments were extracted with acetone. The extract was analyzed by HPLC. Only protochlorophyllide a and no protochlorophyllide b was detected (limit of detection < 1% of protochlorophyllide a). Protochlorophyllide b was synthesized starting from chlorophyll b and incubated with etioplast membranes and NADPH. In the light, photoconversion to chlorophyllide b was observed, apparently catalyzed by NADPH :protochlorophyllide oxidoreductase. In darkness, reduction of the analogue zinc protopheophorbide b to zinc 7-hydroxy-protopheophorbide a was observed, apparently catalyzed by chlorophyll b reductase. We conclude that protochlorophyllide b does not occur in detectable amounts in etioplasts, and even traces of it as the free pigment are metabolically unstable. Thus the direct experimental evidence contradicts the idea by Reinbothe et al. (Nature 397 (1999) 80-84) of a protochlorophyllide b-containing light-harvesting complex in barley etioplasts.
Authors:
V Scheumann; H Klement; M Helfrich; U Oster; S Schoch; W Rüdiger
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  FEBS letters     Volume:  445     ISSN:  0014-5793     ISO Abbreviation:  FEBS Lett.     Publication Date:  1999 Feb 
Date Detail:
Created Date:  1999-04-20     Completed Date:  1999-04-20     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0155157     Medline TA:  FEBS Lett     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  445-8     Citation Subset:  IM    
Affiliation:
Botanisches Institut der Ludwig-Maximilians-Universität München, Germany.
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MeSH Terms
Descriptor/Qualifier:
Hordeum / chemistry*
Molecular Structure
Protochlorophyllide / analysis*
Chemical
Reg. No./Substance:
20369-67-9/Protochlorophyllide

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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