| Properties of metastable linkage NO isomers in Na(2)[Fe(CN)(5)NO]·2H(2)O incorporated in mesopores of silica xerogels. | |
| | |
MedLine Citation:
|
PMID: 22318399 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
|
We study the properties of photoinduced metal-nitrosyl linkage isomers in sodium nitroprusside (SNP) as a function of particle size. By embedding the molecular complex at various concentrations into mesopores of silica xerogels the size of the particles can be adjusted. The ground state is characterized by X-ray diffraction, absorption and infrared spectroscopy. The physical properties of the photoswitched molecules were analysed by steady-state low-temperature absorption, infrared spectroscopy and by nanosecond transient absorption spectroscopy. The electronic structure as well as the activation energies of the metastable linkage isomers are independent of the particle size down to single isolated molecules, indicating that the SNP complexes are quasi-free inside the pores of the gel. |
| | |
Authors:
|
Zakaria Tahri; Robert Lepski; Kuan-Ying Hsieh; El-Eulmi Bendeif; Sebastien Pillet; Pierrick Durand; Theo Woike; Dominik Schaniel |
Related Documents
:
|
10554249 - Incidence of molecular structure in oxidation of grape seed procyanidins. 22375689 - The ion size influence on the ar solvation shells of m+-c6h6 clusters (m=na, k, rb, cs). 11198859 - Manganese citrate chemistry: syntheses, spectroscopic studies, and structural character... 11670259 - Dinuclear (d(3)-d(3)) diolate complexes of molybdenum and tungsten. 3.(1) bridging and ... 12693209 - Synthesis and characterization of new coordination polymers generated from oxadiazole-c... 11670069 - Synthesis and structure of the zintl phase srsn(3)sb(4). 21897929 - Chemical bonding and properties of "layered" quaternary antimonide oxide reoznsb (re = ... 19174849 - Effects of laser radiation on rhus vernicifera laccase, type 2 cu-depleted laccase, and... 12478289 - Bond-controlled configurational entropy reduction in chemical vitrification. |
Publication Detail:
|
Type: JOURNAL ARTICLE Date: 2012-2-8 |
Journal Detail:
|
Title: Physical chemistry chemical physics : PCCP Volume: - ISSN: 1463-9084 ISO Abbreviation: - Publication Date: 2012 Feb |
Date Detail:
|
Created Date: 2012-2-9 Completed Date: - Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 100888160 Medline TA: Phys Chem Chem Phys Country: - |
Other Details:
|
Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
|
CRM2 UMR 7036, Institut Jean Barriol, Université de Lorraine, BP 70239, 54506 Vandoeuvre les Nancy, France. dominik.schaniel@crm2.uhp-nancy.fr. |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Inheritance and genetic mapping of two nuclear genes involved in nuclear-cytoplasmic incompatibility...
Next Document: Factors associated with failure to correct the international normalised ratio following fresh frozen...