Document Detail


Production of 10-hydroxystearic acid from oleic acid and olive oil hydrolyzate by an oleate hydratase from Lysinibacillus fusiformis.
MedLine Citation:
PMID:  22189865     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A recombinant enzyme from Lysinibacillus fusiformis was expressed, purified, and identified as an oleate hydratase because the hydration activity of the enzyme was the highest for oleic acid (with a k (cat) of 850 min(-1) and a K (m) of 540 μM), followed by palmitoleic acid, γ-linolenic acid, linoleic acid, myristoleic acid, and α-linolenic acid. The optimal reaction conditions for the enzymatic production of 10-hydroxystearic acid were pH 6.5, 35 °C, 4% (v/v) ethanol, 2,500 U ml(-1) (8.3 mg ml(-1)) of enzyme, and 40 g l(-1) oleic acid. Under these conditions, 40 g l(-1) (142 mM) oleic acid was converted into 40 g l(-1) (133 mM) 10-hydroxystearic acid for 150 min, with a molar yield of 94% and a productivity of 16 g l(-1) h(-1), and olive oil hydrolyzate containing 40 g l(-1) oleic acid was converted into 40 g l(-1) 10-hydroxystearic acid for 300 min, with a productivity of 8 g l(-1) h(-1).
Authors:
Bi-Na Kim; Young-Chul Joo; Yeong-Su Kim; Kyoung-Rok Kim; Deok-Kun Oh
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2011-12-22
Journal Detail:
Title:  Applied microbiology and biotechnology     Volume:  95     ISSN:  1432-0614     ISO Abbreviation:  Appl. Microbiol. Biotechnol.     Publication Date:  2012 Aug 
Date Detail:
Created Date:  2012-07-26     Completed Date:  2012-11-26     Revised Date:  2012-11-27    
Medline Journal Info:
Nlm Unique ID:  8406612     Medline TA:  Appl Microbiol Biotechnol     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  929-37     Citation Subset:  IM    
Affiliation:
Department of Bioscience and Biotechnology, Konkuk University, Seoul, Republic of Korea.
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MeSH Terms
Descriptor/Qualifier:
Bacillaceae / enzymology*
Base Sequence
Cloning, Molecular
DNA Primers
Electrophoresis, Polyacrylamide Gel
Gas Chromatography-Mass Spectrometry
Hydro-Lyases / chemistry,  genetics,  metabolism*
Hydrogen-Ion Concentration
Hydrolysis
Kinetics
Molecular Weight
Oleic Acid / metabolism*
Plant Oils / metabolism*
Polymerase Chain Reaction
Stearic Acids / metabolism*
Chemical
Reg. No./Substance:
0/DNA Primers; 0/Plant Oils; 0/Stearic Acids; 112-80-1/Oleic Acid; 638-26-6/10-hydroxystearic acid; 8001-25-0/olive oil; EC 4.2.1.-/Hydro-Lyases
Comments/Corrections
Erratum In:
Appl Microbiol Biotechnol. 2012 Aug;95(4):1095-6

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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