| Prilezhaev Dihydroxylation of Olefins in a Continuous Flow Process. | |
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MedLine Citation:
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PMID: 22134987 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Epoxidation of both terminal and non-terminal olefins with peroxy acids is a well-established and powerful tool in a wide variety of chemical processes. In an additional step, the epoxide can be readily converted into the corresponding trans-diol. Batch-wise scale-up, however, is often troublesome because of the thermal instability and explosive character of the peroxy acids involved. This article describes the design and semi-automated optimization of a continuous flow process and subsequent scale-up to preparative production volumes in an intrinsically safe manner. |
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Authors:
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Bas A M W van den Broek; René Becker; Florian Kössl; Mariëlle M E Delville; Pieter J Nieuwland; Kaspar Koch; Floris P J T Rutjes |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-12-1 |
Journal Detail:
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Title: ChemSusChem Volume: - ISSN: 1864-564X ISO Abbreviation: - Publication Date: 2011 Dec |
Date Detail:
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Created Date: 2011-12-2 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101319536 Medline TA: ChemSusChem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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FutureChemistry Holding BV, Toernooiveld 100, 6525 EC Nijmegen (The Netherlands). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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