Document Detail

Pressure-induced phase transition in LiLuF(4):Pr(3+) investigated by an optical technique.
MedLine Citation:
PMID:  22356877     Owner:  NLM     Status:  In-Data-Review    
The luminescence and luminescence kinetics of LiLuF(4) doped with 1.5 at.% of Pr(3+) obtained at high hydrostatic pressure changing from ambient to 220 kbar applied in a diamond anvil cell are presented. It has been shown that pressure causes shift of the emission lines toward the red with rates of the order of single cm(-1) kbar(-1). The pressure-induced phase transition from tetragonal to fergusonite structure for pressure above 100 kbar was observed. The crystal field calculations performed showed that this phase transition reduces the point symmetry of the Pr(3+) site from the S(4) to the C(2) point group.
A Lazarowska; S Mahlik; M Krosnicki; M Grinberg; M Malinowski
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Publication Detail:
Type:  Journal Article     Date:  2012-02-23
Journal Detail:
Title:  Journal of physics. Condensed matter : an Institute of Physics journal     Volume:  24     ISSN:  1361-648X     ISO Abbreviation:  J Phys Condens Matter     Publication Date:  2012 Mar 
Date Detail:
Created Date:  2012-03-02     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101165248     Medline TA:  J Phys Condens Matter     Country:  England    
Other Details:
Languages:  eng     Pagination:  115502     Citation Subset:  IM    
Institute of Experimental Physics, University of Gdańsk, Wita Stwosza 57, 80-952 Gdańsk, Poland.
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