| Pressure-Driven Bipolar Electrochemistry. | |
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MedLine Citation:
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PMID: 21405016 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Here we report that pressure-driven flow alone (no external electrical energy) can be used to drive faradaic electrochemical reactions in microchannels with charged walls. Specifically, we show that solution flow can generate streaming potentials on the order of volts and that this is sufficient to carry out reactions on the anodic and cathodic poles of a bipolar electrode (BPE). The existence of faradaic reactions is proven by electrodissolution of Ag from the anodic end of the BPE. |
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Authors:
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Ioana Dumitrescu; Robbyn K Anand; Stephen E Fosdick; Richard M Crooks |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-3-15 |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: - ISSN: 1520-5126 ISO Abbreviation: - Publication Date: 2011 Mar |
Date Detail:
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Created Date: 2011-3-16 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry and Biochemistry, Center for Electrochemistry, Center for Nano- and Molecular Science and Technology, The University of Texas at Austin , 1 University Station, A5300, Austin, Texas 78712-0165, United States. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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