Document Detail


Preparation and pharmacodynamics of stearic acid and poly (lactic-co-glycolic acid) grafted chitosan oligosaccharide micelles for 10-hydroxycamptothecin.
MedLine Citation:
PMID:  20420886     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Stearic acid (SA) and poly (lactic-co-glycolic acid) (PLGA) grafted chitosan oligosaccharide (SA-CSO-PLGA SCP) tripolymer was synthesized via the reaction between the carboxyl group of SA or PLGA with carboxylic side group, and the amine group of CSO in the presence of 1-Ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC). The degrees of amino-substitution for SA and PLGA were assayed through 2, 4, 6-trinitrobenzene sulfonic acid (TNBS) test and (13)C NMR spectrum, which were 8.15% and 5.82%, respectively; the critical micelle concentrations of SCP in PBS (pH 7.4) and deionized water (DI water) were about 34.9 and 14.5 microg/ml, respectively. Using 10-hydroxycamptothecin (HCPT) as a model drug, the drug-loaded micelles showed above 86% encapsulation efficiency, which not only enhanced the solubility of HCPT in aqueous medium markedly, but also protected the lactone ring of HCPT. Cellular uptakes of SCP micelles against A549, MCF-7 and HepG-2 tumor cells showed a faster cellular internalization. Comparing to the commercial HCPT injection, HCPT-loaded micelles showed higher cytotoxicities against A549, MCF-7 and HepG-2 cells. The increased folds were 22, 18 and 15, respectively. These results suggested the SCP could be applied as a carrier for hydrophobic drugs.
Authors:
Yue-Yu Zhou; Yong-Zhong Du; Ling Wang; Hong Yuan; Jian-Ping Zhou; Fu-Qiang Hu
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2010-04-24
Journal Detail:
Title:  International journal of pharmaceutics     Volume:  393     ISSN:  1873-3476     ISO Abbreviation:  Int J Pharm     Publication Date:  2010 Jun 
Date Detail:
Created Date:  2010-06-01     Completed Date:  2010-09-03     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7804127     Medline TA:  Int J Pharm     Country:  Netherlands    
Other Details:
Languages:  eng     Pagination:  143-51     Citation Subset:  IM    
Copyright Information:
2010 Elsevier B.V. All rights reserved.
Affiliation:
Department of Pharmaceutics, China Pharmaceutical University, 24 Tongjiaxiang Road, Nanjing 210009, PR China.
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MeSH Terms
Descriptor/Qualifier:
Antineoplastic Agents, Phytogenic / chemistry,  metabolism,  pharmacology*
Biological Transport
Camptothecin / analogs & derivatives*,  chemistry,  metabolism,  pharmacology
Carbodiimides / chemistry
Cell Survival / drug effects
Chemistry, Pharmaceutical
Chitosan / analogs & derivatives,  chemical synthesis*
Dose-Response Relationship, Drug
Drug Carriers*
Drug Compounding
Drug Stability
Hep G2 Cells
Humans
Hydrophobicity
Kinetics
Lactic Acid / chemical synthesis*
Magnetic Resonance Spectroscopy
Micelles*
Particle Size
Polyglycolic Acid / chemical synthesis*
Solubility
Stearic Acids / chemical synthesis*
Technology, Pharmaceutical / methods
Chemical
Reg. No./Substance:
0/1-ethyl-3-(3-(diethylamino)propyl)carbodiimide; 0/Antineoplastic Agents, Phytogenic; 0/Carbodiimides; 0/Drug Carriers; 0/Micelles; 0/Stearic Acids; 0/polylactic acid-polyglycolic acid copolymer; 26009-03-0/Polyglycolic Acid; 50-21-5/Lactic Acid; 57-11-4/stearic acid; 67656-30-8/10-hydroxycamptothecin; 7689-03-4/Camptothecin; 9012-76-4/Chitosan

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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