| Preparation of fullerendione through oxidation of vicinal fullerendiol and intramolecular coupling of the dione to form hemiketal/ketal moieties. | |
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MedLine Citation:
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PMID: 16408894 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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[reaction: see text] Vicinal fullerendiol is oxidized to fullerendione in good yield by (diacetoxy)iodobenzene. The resulting cage-opened fullerendione reacts with oxygen nucleophiles in the presence of BF(3).Et(2)O to form fullerene hemiketal/ketal derivatives through coupling of the two carbonyl groups. Fullerene-mixed peroxide derivatives are involved in all these reactions. The compounds are characterized by spectroscopic data and single-crystal X-ray analysis. |
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Authors:
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Shaohua Huang; Fudong Wang; Liangbing Gan; Gu Yuan; Jiang Zhou; Shiwei Zhang |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Organic letters Volume: 8 ISSN: 1523-7060 ISO Abbreviation: Org. Lett. Publication Date: 2006 Jan |
Date Detail:
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Created Date: 2006-01-13 Completed Date: 2006-10-04 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 277-9 Citation Subset: - |
Affiliation:
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Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing, China. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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