Document Detail

Preparation and X-ray structures of 3-[Bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid: new recyclable hypervalent iodine reagents.
MedLine Citation:
PMID:  18062703     Owner:  NLM     Status:  MEDLINE    
Preparation, structural characterization, and reactivity of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid, new recyclable iodine(III) reagents derived from 3-iodosylbenzoic acid, are described. The reduced form of these reagents, 3-iodobenzoic acid, can be easily recovered from the reaction mixtures using ion-exchange resin or basic aqueous workup followed by acidification with HCl.
Mekhman S Yusubov; Tatyana V Funk; Ki-Whan Chi; Eun-Hye Cha; Ghyung Hwa Kim; Andreas Kirschning; Viktor V Zhdankin
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.     Date:  2007-12-07
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  73     ISSN:  0022-3263     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2008 Jan 
Date Detail:
Created Date:  2007-12-28     Completed Date:  2008-03-19     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  295-7     Citation Subset:  IM    
The Siberian State Medical University and The Tomsk Polytechnic University, 2 Moskovsky trakt, 634050 Tomsk, Russia.
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MeSH Terms
Benzoic Acids / chemical synthesis*,  chemistry*
Crystallography, X-Ray
Hydrocarbons, Iodinated / chemical synthesis*,  chemistry*
Indicators and Reagents / chemical synthesis,  chemistry
Models, Molecular
Molecular Structure
Tosyl Compounds / chemical synthesis*,  chemistry*
Reg. No./Substance:
0/3-(bis(trifluoroacetoxy)iodo)benzoic acid; 0/3-(hydroxy(tosyloxy)iodo)benzoic acid; 0/Benzoic Acids; 0/Hydrocarbons, Iodinated; 0/Indicators and Reagents; 0/Tosyl Compounds

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